Let the radius of the spheres = 1.
Inside is a tetrahedron whose vertices are the centers
of the spheres. Its edge length = 2
and its volume = (1/8) √3
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On each face of the tetrahedron, build a triangular prism.
Volume of each prism = (1/2) 2 (√3) 1
Total volume of four prisms = 4√3
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On each edge of the tetrahedron, build a cylindrical sector.
The angle of the sector = 360 – 90 – 90 – dihedral angle of the tetrahedron
= 360 – 90 – 90 – arccos (1/3) = approx. 109.47°
Length of each cylindrical sector = 2, radius = 1
Total volume of the six sectors
Finally, there are pieces of the four original spheres that are not covered by any of the above. The four pieces together make one complete sphere, V = (4/3)π.
Total volume is the sum
tetrahedron + 4 prisms + 6 cylindrical sectors + sphere
= approx. 23.52
Inside is a tetrahedron whose vertices are the centers
of the spheres. Its edge length = 2
and its volume = (1/8) √3

On each face of the tetrahedron, build a triangular prism.
Volume of each prism = (1/2) 2 (√3) 1
Total volume of four prisms = 4√3
On each edge of the tetrahedron, build a cylindrical sector.
The angle of the sector = 360 – 90 – 90 – dihedral angle of the tetrahedron
= 360 – 90 – 90 – arccos (1/3) = approx. 109.47°
Length of each cylindrical sector = 2, radius = 1
Total volume of the six sectors
= 6 π (1^2) 2 (109.47 / 360) ≈ 11.46
Total volume is the sum
tetrahedron + 4 prisms + 6 cylindrical sectors + sphere
= approx. 23.52
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